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Electrochemical Noise:

Electrochemical noise refers to naturally occurring fluctuations in corrosion potential and corrosion current flow. It does not refer to an acoustic measurement. Electrochemical noise (EN) monitoring can be further subdivided into electrochemical potential noise (EPN) measurements and electrochemical current noise (ECN) measurements. The combined monitoring of potential and current is particularly useful. Fluctuations in the corrosion potential can indicate a change in the thermodynamic state of corrosion processes, as for example indicated on a Pourbaix diagram*, while changes in the current noise is an indicator of the corrosion kinetics. The combination of potential and current noise measurements has also been used to estimate corrosion rates; the methodology is related to measuring the well-known polarization resistance Rp.

More information on noise analysis

Electrochemical noise data can provide an indication of the type of corrosion damage that is occurring; it is widely used to distinguish between general and localized attack. The severity of localized can also be gauged by the number and shape of the noise transients. This is an important advantage over other electrochemical techniques. Further fundamental advantages include the ability to monitor corrosion in low conductivity environments (for example, thin film condensation) and the absence of "artificial" polarization effects. Noise measurements are made in the completely "natural" (freely corroding) state.


* credit to P.R. Roberge for this observation

References/Literature:

"Electrochemical Noise Measurement for Corrosion Applications", ASTM Symposium on Electrochemical Noise, Montreal, May 1994, ASTM STP 1277, 1996.

J. Hickling, J. Goellner, A. Burkert and A. Heyn: "Evaluation of a Round Robin Experiment on Electrochemical Noise", Paper #385, Corrosion 98 (San Diego), NACE International, Houston, 1998.

 

Links:
Detailed industrial case history at:
www.hanford.gov/twrs/corrosion/ecn.htm

"State-of-the-Art Review of Electrochemical Noise Sensors" by G.R. Holcomb, B.S. Covino, Jr. and D. Eden on web site of NETL, United States Department of Energy at:
http://www.netl.doe.gov/scng/publications/ENStateoftheArt.pdf

Images of electrochemical noise probes at:
www.tanks.org/BrowsePhotosSingle.asp?PhotoID=76
www.tanks.org/BrowsePhotosSingle.asp?PhotoID=29

 

    

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