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Intergranular corrosion refers to preferential (localized) corrosion along grain boundaries. Grains are "crystals", usually on a microscopic scale, that constitute the (micro)structure of metals and alloys. This selective dissolution may lead to the dislodgement of grains. Intergranular corrosion in sensitized stainless steels and exfoliation in aluminum alloys represent industrially significant examples of this form of damage.

It is difficult to detect intergranular corrosion in its early stages, when the overall loss of thickness remains minimal. Coupon exposures and microscopic examination of surfaces/metallograhic cross sections may be used. Standardized laboratory coupon tests are available to screen out susceptible alloys for quality control purposes.  

 

References/Literature:

"Intergranular Corrosion of Stainless Alloys", ASTM STP 656, American Society for Testing and Materials, West Conshohocken, PA, 1978.

Links:
Examples of intergranular corrosion and exfoliation presented by Kennedy Space Center at:
http://corrosion.ksc.nasa.gov/html/intercor.htm

 

 

    

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E-mail: tullmin@sympatico.ca