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Galvanic Series in Seawater:

This well known series indicates the relative nobility of different metals and alloys in seawater, based on the measurement of corrosion potentials. In a galvanic cell, the more noble material in this series will become the cathode (no metal dissolution), while the less noble material will corrode as the anode. A greater separation of the materials in the galvanic series indicates a bigger potential difference between the materials; generally indicating a greater degree of galvanic incompatibility when coupled. 

Note that this galvanic series was derived for one specific electrolyte (seawater) only. The materials can have a different nobility ranking in different environments and at different temperatures. The series is based on (averaged) corrosion potential data and therefore does not give a direct indication of the rate of galvanic corrosion.  Selected metals/alloys are shown below in a simplified version of this series:

Noble, cathodic end

Platinum
Gold
Graphite
Titanium
Silver
Hastelloy C
18-8 austenitic stainless steels (passive condition)
Iron-chromium alloys (passive condition)
Inconel (passive)
Nickel
Monel
Cupronickel alloys
Bronzes
Copper
Brasses
Inconel (active)
Nickel (active)
Tin
Lead
18-8 Austenitic stainless steels (active)
13% Chromium stainless steel (active)
Cast iron
Mild steel and iron
Cadmium
Aluminum alloys
Zinc
Magnesium and magnesium alloys

Active, anodic end


The position of individual alloys within an alloy family depends on their more specific chemical composition. For example, more detailed series have been published to show the relative positions of different aluminum alloys, bronzes and austenitic stainless steels. The difference in position of certain alloys, depending on their active or passive surface conditions, should be noted.

References/Literature:

ASTM G82 Standard: Guide for Development and Use of a Galvanic Series for Predicting Galvanic Corrosion Performance, American Society for Testing and Materials, West Conshohocken (PA).

Links:
Detailed galvanic series on the web site of McNally Institute:
www.mcnallyinstitute.com/Charts/galvanic-series.html

Galvanic corrosion information in corrosion-club.com.

 

 

    

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