 Crevice corrosion is a localized form of
corrosion, under the influence of "crevice geometries". Well-known examples of
such geometries include flanges, gaskets, disbonded linings/coatings, fasteners, lap
joints and surface deposits. Stagnant solution plays an important role in setting up of
highly corrosive micro-environments inside such crevices. A metallic material tends to
assume a more anodic character in the stagnant crevice solution compared with the bulk
surface (exposed to the bulk environment).
As in pitting attack, systems relying on passive surface films for
corrosion resistance can be particularly vulnerable to this mode of corrosion. The highly
corrosive micro-environment of crevices tends to be similar to the micro-environment
established at the base of corrosion pits. Crevice corrosion is associated with induction
(initiation) and propagation phases.
Usually, the detection and meaningful
monitoring of crevice corrosion represents a major challenge. Crevice corrosion
geometries, such as the lap joints on aircraft fuselages, represent classic examples of
"hidden" corrosion.
One approach to monitoring crevice corrosion is the use of corrosion
sensors fitted with artificial crevices. Difficulties with this methodology lie in the
areas of reproducibility and of simulating actual in-service crevices. The use of
specimens with a relatively large number of artificial crevices to facilitate statistical
evaluations has therefore been advocated. |
A more recent approach has been to incorporate
micro-sensors inside the corrosive micro-environments of crevice geometries. The use of
fiber optic sensors and micro-electrodes has been introduced for these purposes.
Most corrosion scientists and engineers are all too familiar with unwanted
crevice effects occurring on corrosion probes that are designed to monitor other
forms of corrosion damage. The interface between the sensor element and the probe body can
be particularly prone to undesirable crevice attack, resulting in extraneous corrosion
signals. This frustrating problem can also occur where electronic leads are attached to
certain corrosion sensors.
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